By S. S. Labana
content material: Formation and houses of polymer networks : experimental and theoretical stories / J.L. Stanford, R.F.T. Stepto, and R.H. nonetheless --
machine simulation of end-linked elastomers : sol-gel distributions at excessive extents of response / Yu-Kwan Leung and B.E. Eichinger --
Rheological alterations through the copolymerization of vinyl and divinyl monomers / D.T. Landin and C.W. Macosko --
Elastomeric poly(dimethylsiloxane) networks with various short-chain segments / J.E. Mark and J.G. Curro --
mild scattering of randomly cross-linked polystyrene / Kanji Kajiwara and Walther Burchard --
Correlation networks in polymeric fabrics made up our minds by means of small-angle neutron scattering / L.H. Sperling, A.M. Fernandez, and G.D. Wignall --
Carboxyl-terminated butadiene-acrylonitrile-modified epoxy resin and its graphite fiber-reinforced composite : morphology and dynamic mechanical homes / Su-Don Hong, Shirley Y. Chung, George Neilson, and Robert F. Fedors --
Mechanical habit of a few epoxies with epoxidized ordinary oils as reactive diluents / Shahid Qureshi, J.A. Manson, J.C. Michel, R.W. Hertzberg, and L.H. Sperling --
quantity restoration in aerospace epoxy resins : results on time-dependent houses of carbon fiber-reinforced epoxy composites / Eric S.W. Kong --
constitution and fracture of hugely cross-linked networks / J.D. Lemay, B.J. Swetlin, and F.N. Kelley --
Fractographic impact of glassy natural networks / D.T. Turner --
Peroxide cross-linked average rubber and cis-polybutadiene : characterization by way of high-resolution solid-state carbon-13 NMR / Dwight J. Patterson and Jack L. Koenig --
Carbon-13 magic attitude NMR spectroscopic stories of an epoxy resin community / A. Cholli, W.M. Ritchey, and Jack L. Koenig --
NMR kinetic research of polyethylene-peroxide cross-linking reactions / V.D. McGinniss and J.R. Nixon --
Degradation chemistry of fundamental cross-links in high-solids the teeth finishes : solar-assisted hydrolysis / Alan D. English and Harry J. Spinelli --
IR spectroscopic reports of decay in cross-linked networks : photoenhanced hydrolysis of acrylic-melamine coatings / D.R. Bauer and L.M. Briggs --
Electron spin resonance (ESR) of photodegradation in polymer networks : photoinitiation fee size via nitroxide termination / John L. Gerlock, David R. Bauer, and L.M. Briggs --
hugely cross-linked CR-39 polycarbonate and its degradation via high-energy radiation / J.L. Cercena, J. Groeger, A.A. Mehta, R. Prottas, J.F. Johnson, and S.J. Huang.
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Extra info for Characterization of Highly Cross-linked Polymers
As discussed previously, this is not valid for vinyl-divinyl copolymerization. A revision of this recursive theory to include the effects of cyclization i s necessary. Using the same i n i t i a l procedure as In (18), the vinyl-divinyl copolymerization is thought of as: \ + A 2 polymer where A4 i s divinyl and A2 i s v i n y l . A quantity q i s defined as the probability that an initiated radical chain w i l l add one more monomer unit and ρ is the conversion of vinyl groups. 999. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1984.
Macromolecules 1979, 12, 521. 3. Hickey, W. ; Macosko, C. W. ACS Polymer Preprints 1981, 22, No. 2, 579; Hickey, W. J. S. Thesis, University of Minnesota 1980. 4. Valles, Ε. ; Macosko, C. W. Macromolecules 1979, 12. 5. Macosko, C. ; Benjamin, G. S. Pure Appl. Chem. 1981, 53, 1505. 6. Gottlieb, M; Macosko, C. ; Lepsch, T. C. Polym. Phys. Ed. 1981, 19, 1603-1067; reprinted in Rubber Chem. & Techn. 1982, 55, 1108. 7. Gottlieb, M; Macosko, C. ; Benjamin, G. , Meyers, Κ. ; Merrill, E. W. Macromolecules 1981, 14, 1039; portions in Polymer Preprints 1981, 22, No.
S p e c i f i c a l l y , Monte Carlo c a l c u l a t i o n s (22-24) based on the r o t a t i o n a l isomeric s t a t e approximation (21) are used to simulate spatial configurations, and thus distribution functions f o r the end-to-end separation r o f the network chains. These d i s t r i b u t i o n functions may be used i n place o f the Gaussian f u n c t i o n to give a molecular theory o f r u b b e r l i k e elasticity which i s unique to the p a r t i c u l a r polymer o f interest, and a p p l i c a b l e to the regions o f very large deformation, where the bimodal networks e x h i b i t t h e i r h i g h l y unusual p r o p e r t i e s .
Characterization of Highly Cross-linked Polymers by S. S. Labana