Zhen-Zhen Yang's Capture and Utilization of Carbon Dioxide with Polyethylene PDF

By Zhen-Zhen Yang

ISBN-10: 3642312675

ISBN-13: 9783642312670

In this quantity, Professor He and his coworkers summarize polyethylene glycol (PEG)-promoted CO2 chemistry at the foundation of realizing approximately section habit of PEG/CO2 method and response mechanism at molecular point. As PEG may be applied as a eco-friendly substitute for natural solvents, phase-transfer catalyst, surfactant, aid in quite a few response structures, considerably selling catalytic job and recuperating dear steel catalysts, rather considered as a CO2-philic fabric, the authors concentrate on specified functions of PEG in CO2 trap and usage, together with PEG-functionalized catalysts for effective transformation of CO2 and PEG-functionalized absorbents for effective CO2 trap.
Furthermore, they describe carbon trap and usage technique as a substitute method of tackle the strength penalty challenge in carbon seize and garage.
Interestingly, the authors additionally talk about PEG radical chemistry in dense CO2 as quite inventive and weird use of PEG, most likely serves as a response medium and an intensive initiator for radical chemistry.

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Extra info for Capture and Utilization of Carbon Dioxide with Polyethylene Glycol

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Blanchard LA, Hancu D, Beckman EJ et al (1999) Green processing using ionic liquids and CO2. Nature 399(6731):28–29 7. Blanchard LA, Brennecke JF (2000) Recovery of organic products from ionic liquids using supercritical carbon dioxide. Ind Eng Chem Res 40(1):287–292 8. Brown RA, Pollet P, McKoon E et al (2001) Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide. J Am Chem Soc 123(6): 1254–1255 9. Liu F, Abrams MB, Baker RT et al (2001) Phase-separable catalysis using room temperature ionic liquids and supercritical carbon dioxide.

Caravati M, Grunwaldt J-D, Baiker A (2005) Benzyl alcohol oxidation in supercritical carbon dioxide: spectroscopic insight into phase behaviour and reaction mechanism. Phys Chem Chem Phys 7(2):278–285 73. Bergbreiter DE (2002) Using soluble polymers to recover catalysts and ligands. Chem Rev 102(10):3345–3384 74. Sandee AJ, Reek JNH, Kamer PCJ et al (2001) A silica-supported, switchable, and recyclable hydroformylation–hydrogenation catalyst. J Am Chem Soc 123(35):8468–8476 75. Shibahara F, Nozaki K, Hiyama T (2003) Solvent-free asymmetric olefin hydroformylation catalyzed by highly cross-linked polystyrene-supported (R, S)-BINAPHOS–Rh(I) complex.

ChemSusChem 2(8):755–760 83. Seki T, Grunwaldt J-D, Baiker A (2007) Continuous catalytic ‘‘one-pot’’ multi-step synthesis of 2-ethylhexanal from crotonaldehyde. Chem Commun 34:3562–3564 84. Wang J-Q, He L-N, Miao C-X (2009) Polyethylene glycol radical-initiated oxidation of benzylic alcohols in compressed carbon dioxide. , coal-fired power plants, represents a critical component of efforts aimed at stabilizing greenhouse gas levels in the atmosphere. In addition, removal of CO2 from natural gas is of vital importance to maintain and expand the availability of these clean-burning, efficient fuel sources.

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Capture and Utilization of Carbon Dioxide with Polyethylene Glycol by Zhen-Zhen Yang

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