Get Advances in Inorganic Chemistry, Vol. 55 PDF

By Rudi van Eldik

ISBN-10: 0120236559

ISBN-13: 9780120236558

Advances in Inorganic Chemistry offers well timed and informative summaries of the present development in a number of topic components inside of inorganic chemistry starting from bio-inorganic to strong country experiences. Thisacclaimed serial positive factors experiences written via specialists within the sector and is an imperative connection with complicated researchers. every one quantity of Advances in Inorganic Chemistry comprises an index, and every bankruptcy is absolutely referenced. . accomplished stories written by means of best specialists within the box . An necessary connection with complicated researchers . contains 7 contributions protecting vital advances in inorganic chemistry

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Rev. 2000, 200^202, 443^485. 15. ; Gherman, B. ; Lippard, S. ; Friesner, R. A. Curr. Op. Chem. Biol. 2002, 6, 236^242. 16. Kopp, D. ; Lippard, S. J. Curr. Op. Chem. Biol. 2002, 6, 568^576. 17. Lipscomb, J. ; Que, L. Jr. J. Biol. Inorg. Chem. 1998, 3, 331^336. 18. Shteinman, A. A. J. Biol. Inorg. Chem. 1998, 3, 325^330. 19. Que, L. ; Tolman, W. B. Angew. Chem. Int. Ed. 2002, 41, 1114^1137. 20. Blackman, A. ; Tolman, W. B. Struct. Bonding (Berlin) 2000, 97 (Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations), 179^211.

The reaction between HNO2 and L2(H2O)RhOO2 þ generated the nitrato intermediate, L2(H2O)Rh(NO3)2 þ , but the yield was only half of that observed earlier in the NO/L2(H2O)RhOO2 þ reaction. ATOM TRANSFER AND FREE RADICAL CHEMISTRY 41 SCHEME 12. The reduced yield is consistent with the proposal in Scheme 12, according to which only 50% of L2(H2O)RhOO2 þ reacts with NO, the other 50% being consumed by NO2, Eqs. (52)^(53). The reaction in Eq. (52) was written in analogy to the directly observed NO2/CraqOO2 þ reaction, see below.

This step is in agreement with literature precedents (133^137) and with the recent discussion of delocalization of electron density in phenoxyl radicals (138). The peroxochromium intermediate was not observed, implying that the dissociation of CraqOH2 þ in the next step is fast. Finally, the loss of tert-butanol was written in analogy with the known reactions in organic solvents (139,140). 3. Pivaldehyde (CMe3CHO) In aqueous solutions pivaldehyde exists as a 4:1 mixture of CMe3CHO and CMe3CH(OH)2 (141).

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Advances in Inorganic Chemistry, Vol. 55 by Rudi van Eldik


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