Download e-book for iPad: Advances in Heterocyclic Chemistry, Vol. 11 by A.R. Katritzky, A.J. Boulton (Eds.)

By A.R. Katritzky, A.J. Boulton (Eds.)

ISBN-10: 0120206110

ISBN-13: 9780120206117

(from preface)This, the 11th quantity of Advances in Heterocyclic Chemistry, comprises surveys of the chemistry of the subsequent teams of heterocyclic compounds: benzo[6]thiophenes (B. Iddon and R. M. Scrow-ston), naphthyridines (W. W. Paudler and T. J. Kress), and quinu-clidines (L. N. Yakhontov). moreover, R. A. Jones covers the appliance of actual the right way to pyrrole chemistry and a really topical topic, the photochemistry of heterocycles, is reviewed by way of S. T. Reid.Suggestions are welcomed for contributions to destiny volumes; they need to be within the type of brief sj'nopses.Thanks are because of the Editorial Board, the writer, and the authors for his or her cooperation.

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Chem. SOC. 89, 3501 (1967). 134K. 111. ] 39 THE PHOTOCHEMISTRY OF HETEROCYCLES mediate (151) is known to be involved in the rearrangement of 3,5diphenylisoxazole (152) to 2,5-diphenyloxazole ( 153),13e and in (152) (151) (153) similar rearrangements of other isoxazoles. 13’, 13* Isolation of the intermediate has finally been achieved in the conversion of 2,5-di-tbutylfuran into 2,4-di-t-butylfuran [Eq. l~~ E. F. Ullman and B. Singh, J . Am. Chem. 88, 1844 (1966). D. W. Kurtz and H. Shechter, Chern.

J. Becher, and C. Lohse, Acta Chem. Scand 19, 1120 (1965). 152 J. K. Landquist, J. Chem. Soc. 2830 (1953). 153 G. B. Brown, G. Levin, and S. Murphy, Biochemistry 3, 880 (1964). 154 M. Ishikawa, S. Yamada, H. Hotta, and C. Kaneko, Chem. Pharm. Bull. (Tokyo)14, 1102 (1966). 155 E. C. Taylor and G. G. Spence, Chem. Commun. 767 (1966). 156 E. C. Taylor and G. G. Spence, Chem. Commun. 1037 (1968). 150 N. 151 0. 111. ] THE PHOTOCHEMISTRY 45 OF HETEROCYCLES Migration accompanying the cleavage of an oxaziridine is also involved in the rearrangement in high yield of 2-benzoyl-3-phenylquinoxaline 1,kdioxide (183) to the benzimidazolone (184) on photolysis in methanol.

A. Paquette. J. Am. Chem. SOC. 86, 500 (1964). 104 R. F. Childs and A. W. Johnson, J. Chem. , C 874 (1967). W. J. Theuer and J. A. Moore, Chem. Comnzun. 408 (1965). 106 A. G. Anastassiou and R. P. Cellura, Chem. Commun. 762 (1967). 107 G . J. Fonken, Chem. & Ind. (London) 1575 (1961). 105 32 [SEC. S. T. REID 111. E. l0*Oxepin itself (124) is isomerized to the oxabicycloheptadiene (125) on irradiation in ether solution, but in acetone solution, phenol is the principal p h o t o p r o d ~ c tThere .

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Advances in Heterocyclic Chemistry, Vol. 11 by A.R. Katritzky, A.J. Boulton (Eds.)


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