Read e-book online Advances in Chemical Physics (Volume 136) PDF

By Stuart A. Rice

ISBN-10: 0471682322

ISBN-13: 9780471682325

Advances in Chemical Physics is the single sequence of references to be had that explores the leading edge of study in chemical physics. This sequence offers the chemical physics box with a discussion board for serious, authoritative reviews of advances in each region of the self-discipline.

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Low-lying bands, labeled by a ‘‘bent’’ quantum number, vb , which counts the number of nodes in the vibrational wavefunction, have rotational levels that vary smoothly with k, which is the signed value of the a-axis rotational quantum number, Ka . However, bands with origins above the barrier show a smooth energy variation with k only for levels with common values of the ‘‘linear’’ vibrational quantum number vl ¼ 2vb þ jkj, where k is now identified with the bending angular momentum of a linear molecule, often denoted by l.

A. Meijer, E. M. Goldfield, S. K. Gray, and G. G. Balint-Kurti, Chem. Phys. Lett. 293, 270 (1998). 14. G. G. Balint-Kurti, A. I. Gonzalez, E. M. Goldfield, and S. K. Gray, Faraday Discuss. 110, 169 (1998). 15. S. K. Gray and D. E. Manolopoulos, J. Chem. Phys. 104, 7099 (1996). 16. G. Nyman and H. G. Yu, Rep. Prog. Phys. 63, 1001 (2000). 17. D. H. Zhang and J. Z. H. Zhang, J. Chem. Phys. 101, 1146 (1994). 18. D. Neuhauser, J. Chem. Phys. 100, 9272 (1994). 19. F. Gatti, C. Lung, M. Menou, Y. Justum, A.

However, the computation of the Coriolis terms involves communication between processor k and processors k Æ 1. In fact, processor k will send qð:; kÞ to each of its neighboring processors and will receive both qð:; k À 1Þ and qð:; k þ 1Þ from its neighbors. (Processor 0 24 evelyn m. goldfield and stephen k. ) This communication is accomplished through the use of MPI calls, which are given in the appendix of Ref. [32]. One can see that if the cost of communication can be kept to a minimum, this simple model would require little more wall clock time than a J ¼ 0 calculation.

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Advances in Chemical Physics (Volume 136) by Stuart A. Rice

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