Download e-book for iPad: Adsorption on Silica Surfaces by Eugene Papirer

By Eugene Papirer

ISBN-10: 0824700031

ISBN-13: 9780824700034

Offers crucial fabric at the floor and adsorption homes of silica. Progresses from theoretical matters to program, with a historic evaluate, in-depth attention of varied situations of silica adsorption, and effects from fresh examine. Addresses the necessity for particular methods for every form of silica adsorption and uniquely devotes attention to silica adsorption from resolution. particular issues contain floor chemistry utilizing IR and NMR spectroscopies, desktop modeling, micro- and macromolecular species of adsorbents, and the position of silica debris in part transformation of water. The editor is retired study director on the Centre nationwide de l. a. Recherche Scientifique, Institut de Chimie des Surfaces et Interfaces, France.

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Samoson, V. Brei, and Yu. I. Gorlov. Dokl. Akad. R. (Phys. ) 259:403 (1981). E. Bronnimann, R. C. Zeigler, and G. E. Maciel. J. Am. Chem. Soc. 110:2023 59. (1988). 60. D. R. 3. Chuang, and G. E. Maciel. J. Am. Cllern. Soc. 115:6786 (1993). 61. C. Liu and G. E. Maciel. J. Am. Chem. Soc. 103 996). 62. B. C. Gerstein, M. -J. Hwang. Analytica Chimica Acta 283:1059 (1993). 63. Hwang, D. 0. Uner, T. S. King, M. Pruski, and B. C. Gerstein. J. Phys. Chem. 993697 (1995). 64. G. E. Maciel and D. W. Sindorf.

6 they found experimentally in the case of various silica gels. Peri and Hensley [9] visualized the (100) face of p-cristobalite as silicon atoms each connected to a pairof hydroxyl groups located in rows (Fig. 2). Recent studies on silica gels using solid-state Si2' NM have shown that no single previously proposed model gives a completely adequate description of the surface structure of synthesized silica [lo]. The results indicated that silica surface is quite heterogeneous and may contain segments of surface resembling both the (1 11) and (100) faces of cristobalite.

L. Walter, A. Wokaun, and A. Baiker. Mol. Phys. 71:769 (1990). 79 80. U. Darnrau, H. C. Marsmann, 0. Spormann, and P. Wang. J. Non-Cryst, 164 992). 81. R. H. Glaser, G. Wilkes, and C. E. Bronnimann, J. 113:73 (1989). 82. A. J. Vega. J. Magn. Reson. 9650 992). 83. Sun, J. T. Stephen,L. D. Potter, and U. Wu. J. Reson. A 995). A. Morrow and A. Devi. Can. Chem. 48:2454 (1970). 84. 1 1604 85. Rddm, Appelt, R. Seydoux, E. L. Hahn, andA. Pines. Pllys. Rev. B 55: (1997). 86. E. Brunner, R. Seydoux, M. Haake, A.

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