By K. L. Mittal (Eds.)
content material: Thermodynamics of adsorption and interparticle forces / D.H. Everett and C.J. Radke --
Configurational habit of remoted chain molecules adsorbed from athermal ideas / M. Lal, M.A. Turpin, K.A. Richardson, and D. Spencer --
Equilibrium movie strain on a flat, low-energy strong / Robert J. stable --
Binding of solute and solvent on the interface and the gibbs floor extra / D.K. Chattoraj and S.P. Moulik --
Mechanism of sulfonate adsorption on the silver iodide-solution interface / okay. Osseo-Asare, D.W. Fuerstenau, and R.H. Ottewill --
Adsorption of dyes on water-swollen and non-swelling good substrates / S.R. Sivaraja Iyer, A.S. Chanekar, and G. Srinivasan --
Adsorption of polystyrene on graphon from toluene / Victor ok. Dunn and Robert D. Vold --
Adsorption of ionic surfactants to porous glass : the exclusion of micelles and different solutes from adsorbed layers and the matter of adsorption maxima / Pasupati Mukerjee and Aroonsri Anavil --
DTA examine of water in porous glass / Chaur-Sun Ling and W. Drost-Hansen --
Monolayer experiences. five, Styrene-acrylic acid motion pictures on aqueous substrates / Erwin Sheppard and Noubar Tcheurekdjian --
interplay of calcium ions with the combined monolayers of stearic acid and stearyl alcohol at pH 8.8 / D.O. Shah --
touch angles in Newton-Black cleaning soap motion pictures drawn from suggestions containing sodium dodecyl sulphate and electrolyte / J.A. De Feijter and A. Vrij --
Stratification in unfastened liquid motion pictures / J.W. Keuskamp and J. Lyklema --
floor chemical homes of hugely fluorinated polymers / Marianne ok. Bernett and W.A. Zisman --
impression of floor oxygen complexes on floor habit of carbons / Balwant Rai Puri --
floor houses of nickel hydroxide prior to and after dehydration to nickel oxide / M. subject, F.J. Micale, C.L. Cronan, H. Leidheiser, Jr., and A.C. Zettlemoyer --
The dimension of low interfacial pressure through the spinning drop method / J.L. Cayias, R.S. Schechter, and W.H. Wade --
Adhesion of ice frozen from dilute electrolyte options / H.H.G. Jellinek --
Mechanism of olfaction defined utilizing interfacial stress measurements / D.V. Rathnamma --
function of double interactions and spreading strain in particulate soil removing / Hermann Lange.
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Extra info for Adsorption at Interfaces
Graham (4) noted a d i f f i c u l t y a r i s i n g from bulk s o l u b i l i t y of an alkane i n the substrate, such that the quantity sorbed could not be uniquely assigned as between adsorption and absorption. )). 7 erg/cm^, was an upper l i m i t ; he could not estimate the r e a l value. 3 f o r hexane and 2,9 for octane. They e x p l i c i t l y corrected for pendular r i n g condensation, and i n so doing, they obtained estimates of ir i n t h e i r systems that were very probably more v a l i d than Graham's were f o r h i s .
14214 Introduction The equilibrium f i l m pressure of an adsorbate, πe, i s defined as πe = Y S - Y SV (1) where ΥS i s the surface free energy of the s o l i d i n vacuum, and YSV i s the surface free energy of the s o l i d i n contact with the saturated vapor of the ad sorbate. The value of this property for an adsorbate which, as a l i q u i d , forms a non-zero contact angle on the s o l i d , has been a matter of uncertainty for some time (1-9). This fact has detracted from the use fulness of measurements of contact angle, θ, for the estimation of s o l i d surface free energies (2,3).
J . Chem. Soc. Faraday Trans. I I , (1973), 69, 1502. 9. , J . Chem. Soc. Faraday Trans. I I , (1974), 70, 910. 10. , and Cronan, J . Phys. , (1966), 70, 306. 11. , J . Chem. , (1967), 47, 1980. 12. 13. , Mol. , (1969), 17, 57. , Amsterdam, 1968. 14. , t o be p u b l i s h e d . ; ACS Symposium Series; American Chemical Society: Washington, DC, 1975. 3 Equilibrium Film Pressure on a Flat, Low-Energy Solid R O B E R T J. G O O D Department of Chemical Engineering, State University of New York at Buffalo, Buffalo, Ν.
Adsorption at Interfaces by K. L. Mittal (Eds.)